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Validation of the inverted adsorption structure for free-base tetraphenyl porphyrin on Cu(111)
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Ryan, P. T. P., Lalaguna, P. L., Haag, F., Braim, M. M., Ding, P., Payne, D. J., Barth, J. V., Lee, T.-L., Woodruff, D. P., Allegretti, F. and Duncan, D. A. (2020) Validation of the inverted adsorption structure for free-base tetraphenyl porphyrin on Cu(111). Chemical Communications, 56 (25). pp. 3681-3684. doi:10.1039/C9CC09638H
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WRAP-validation-inverted-adsorption-structure-free-base-tetraphenyl-porphyrin-Cu(111)-Woodruff-2020.pdf - Published Version - Requires a PDF viewer. Available under License Creative Commons Attribution. Download (2820Kb) | Preview |
Official URL: http://dx.doi.org/10.1039/C9CC09638H
Abstract
Utilising normal incidence X-ray standing waves we rigourously scrutinise the “inverted model” as the adsorption structure of free-base tetraphenyl porphyrin on Cu(111). We demonstrate that the iminic N atoms are anchored at near-bridge adsorption sites on the surface displaced laterally by 1.1 ± 0.2 Å in excellent agreement with previously published calculations.
| Item Type: | Journal Article | |||||||||
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| Subjects: | Q Science > QD Chemistry Q Science > QP Physiology |
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| Divisions: | Faculty of Science > Physics | |||||||||
| Library of Congress Subject Headings (LCSH): | Porphyrins, Adsorption, Porphyrins -- Absorption and adsorption | |||||||||
| Journal or Publication Title: | Chemical Communications | |||||||||
| Publisher: | Royal Society of Chemistry | |||||||||
| ISSN: | 1359-7345 | |||||||||
| Official Date: | 2 March 2020 | |||||||||
| Dates: |
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| Date of first compliant deposit: | 26 March 2020 | |||||||||
| Volume: | 56 | |||||||||
| Number: | 25 | |||||||||
| Page Range: | pp. 3681-3684 | |||||||||
| DOI: | 10.1039/C9CC09638H | |||||||||
| Status: | Peer Reviewed | |||||||||
| Publication Status: | Published | |||||||||
| Access rights to Published version: | Open Access | |||||||||
| RIOXX Funder/Project Grant: |
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