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Validation of the inverted adsorption structure for free-base tetraphenyl porphyrin on Cu(111)

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Ryan, P. T. P., Lalaguna, P. L., Haag, F., Braim, M. M., Ding, P., Payne, D. J., Barth, J. V., Lee, T.-L., Woodruff, D. P., Allegretti, F. and Duncan, D. A. (2020) Validation of the inverted adsorption structure for free-base tetraphenyl porphyrin on Cu(111). Chemical Communications, 56 (25). pp. 3681-3684. doi:10.1039/C9CC09638H

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Official URL: http://dx.doi.org/10.1039/C9CC09638H

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Abstract

Utilising normal incidence X-ray standing waves we rigourously scrutinise the “inverted model” as the adsorption structure of free-base tetraphenyl porphyrin on Cu(111). We demonstrate that the iminic N atoms are anchored at near-bridge adsorption sites on the surface displaced laterally by 1.1 ± 0.2 Å in excellent agreement with previously published calculations.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Q Science > QP Physiology
Divisions: Faculty of Science > Physics
Library of Congress Subject Headings (LCSH): Porphyrins, Adsorption, Porphyrins -- Absorption and adsorption
Journal or Publication Title: Chemical Communications
Publisher: Royal Society of Chemistry
ISSN: 1359-7345
Official Date: 2 March 2020
Dates:
DateEvent
2 March 2020Published
28 January 2020Accepted
Date of first compliant deposit: 26 March 2020
Volume: 56
Number: 25
Page Range: pp. 3681-3684
DOI: 10.1039/C9CC09638H
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Open Access
RIOXX Funder/Project Grant:
Project/Grant IDRIOXX Funder NameFunder ID
e-conversionClusterofExcellenceEXC2089/1-39077626[DFG] Deutsche Forschungsgemeinschafthttp://dx.doi.org/10.13039/501100001659
UNSPECIFIEDTechnische Universität MünchenUNSPECIFIED

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