The Library
Isolation and structural characterisation of rhodium(III) η2–fluoroarene complexes : experimental verification of predicted regioselectivity
Tools
Gyton, Matthew R., Kynman, Amy E., Leforestier, Baptiste, Gallo, Angello, Lewandowski, Józef R. and Chaplin, Adrian B. (2020) Isolation and structural characterisation of rhodium(III) η2–fluoroarene complexes : experimental verification of predicted regioselectivity. Dalton Transactions, 49 . pp. 5791-5793. doi:10.1039/D0DT01137A ISSN 1477-9226.
|
PDF
WRAP-isolation-structural-characterisation-rhodium-η2–fluoroarene-complexes-Gyton-2020.pdf - Published Version - Requires a PDF viewer. Available under License Creative Commons Attribution Non-commercial. Download (647Kb) | Preview |
|
PDF
WRAP-isolation-structural-characterisation-rhodium(III)-η2–fluoroarene-complexes-Gyton-2020.pdf - Accepted Version Embargoed item. Restricted access to Repository staff only - Requires a PDF viewer. Download (1200Kb) |
Official URL: https://doi.org/10.1039/D0DT01137A
Abstract
The isolation and solid-state characterisation of complexes featuring partially coordinated benzene, fluorobenzene and all three isomers of difluorobenzene are described. Supported by a DFT analysis, this well-defined homologous series demonstrates the preference for η2-coordination of fluoroarenes via the HC[double bond, length as m-dash]CH sites adjacent to a fluorine substituent.
Item Type: | Journal Article | |||||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Subjects: | Q Science > QD Chemistry T Technology > TP Chemical technology |
|||||||||||||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | |||||||||||||||
Library of Congress Subject Headings (LCSH): | Benzene, Organotransition metal compounds, Ruthenium compounds | |||||||||||||||
Journal or Publication Title: | Dalton Transactions | |||||||||||||||
Publisher: | Royal Society of Chemistry | |||||||||||||||
ISSN: | 1477-9226 | |||||||||||||||
Official Date: | 21 April 2020 | |||||||||||||||
Dates: |
|
|||||||||||||||
Volume: | 49 | |||||||||||||||
Page Range: | pp. 5791-5793 | |||||||||||||||
DOI: | 10.1039/D0DT01137A | |||||||||||||||
Status: | Peer Reviewed | |||||||||||||||
Publication Status: | Published | |||||||||||||||
Access rights to Published version: | Open Access (Creative Commons) | |||||||||||||||
Copyright Holders: | © The Royal Society of Chemistry 2020 | |||||||||||||||
Date of first compliant deposit: | 7 April 2020 | |||||||||||||||
Date of first compliant Open Access: | 9 October 2020 | |||||||||||||||
RIOXX Funder/Project Grant: |
|
Request changes or add full text files to a record
Repository staff actions (login required)
View Item |
Downloads
Downloads per month over past year