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Porphyrazinediols: Synthesis, characterization, and complexation to group IVB metallocenes
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UNSPECIFIED (2000) Porphyrazinediols: Synthesis, characterization, and complexation to group IVB metallocenes. JOURNAL OF ORGANIC CHEMISTRY, 65 (6). pp. 1774-1779. ISSN 0022-3263
Full text not available from this repository.Abstract
The first metalated porphyrazinediols 11 have been prepared from (L)-(+)-dimethyl tartrate via conversion into the corresponding dispoke or 2,3-dimethoxy-2,3-butanediyl protected 2,3-dihydroxymaleonitrile, Linstead macrocyclization, transmetalation, and deprotection. Their stability is very dependent on the nature of the metal ion in the cavity of the porphyrazine. Reaction of these porphyrazinediols with metallocene dichlorides led to new solitaire porphyrazines 12 while DDQ oxidation followed by trapping with diaminomaleonitrile afforded new porphyrazine dinitriles 14.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | JOURNAL OF ORGANIC CHEMISTRY |
| Publisher: | AMER CHEMICAL SOC |
| ISSN: | 0022-3263 |
| Date: | 24 March 2000 |
| Volume: | 65 |
| Number: | 6 |
| Number of Pages: | 6 |
| Page Range: | pp. 1774-1779 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/13544 |
Data sourced from Thomson Reuters' Web of Knowledge
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