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Perovskite oxides rpepared by hydrothermal and solvothermal synthesis : a review of crystallisation, chemistry, and compositions
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Walton, Richard I. (2020) Perovskite oxides rpepared by hydrothermal and solvothermal synthesis : a review of crystallisation, chemistry, and compositions. Chemistry - A European Journal, 26 (42). pp. 9041-9069. doi:10.1002/chem.202000707
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WRAP-Perovskite-hydrothermal-solvothermal-synthesis-Walton-2020.pdf - Accepted Version - Requires a PDF viewer. Download (3292Kb) | Preview |
Official URL: http://dx.doi.org/10.1002/chem.202000707
Abstract
Perovskite oxides with general composition ABO3 are a large group of inorganic materials that can contain a variety of cations from all parts of the Periodic Table and that have diverse properties of application in fields ranging from electronics, energy storage to photocatalysis. Solvothermal synthesis routes to these materials have become increasingly investigated in the past decade as a means of direct crystallisation of the solids from solution. These methods have significant advantages leading to adjustment of crystal form from the nanoscale to the micron‐scale, the isolation of compositions not possible using conventional solid‐state synthesis and in addition may lead to scalable processes for producing materials at moderate temperatures. These aspects are reviewed, with examples taken from the past decade’s literature on the solvothermal synthesis of perovskites with a systematic survey of B‐site cations, from transition metals in Groups 4‐8 and main group elements in Groups 13, 14 and 15, to solid solutions and heterostructures. As well as hydrothermal reactions, the use of various solvents and solution additives are discussed and some trends identified, along with prospects for developing control and predictability in the crystallisation of complex oxide materials.
| Item Type: | Journal Article | ||||||||
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| Subjects: | Q Science > QD Chemistry Q Science > QE Geology |
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| Divisions: | Faculty of Science > Chemistry | ||||||||
| Library of Congress Subject Headings (LCSH): | Perovskite , Oxide minerals, Perovskite -- Effect of high temperatures on , High temperature chemistry, Crystallization | ||||||||
| Journal or Publication Title: | Chemistry - A European Journal | ||||||||
| Publisher: | Wiley - V C H Verlag GmbH & Co. KGaA | ||||||||
| ISSN: | 0947-6539 | ||||||||
| Official Date: | 27 July 2020 | ||||||||
| Dates: |
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| Volume: | 26 | ||||||||
| Number: | 42 | ||||||||
| Page Range: | pp. 9041-9069 | ||||||||
| DOI: | 10.1002/chem.202000707 | ||||||||
| Status: | Peer Reviewed | ||||||||
| Publication Status: | Published | ||||||||
| Publisher Statement: | "This is the peer reviewed version of the following article: Walton, R..I. (2020), Perovskite Oxides Prepared by Hydrothermal and Solvothermal Synthesis: a Review of Crystallisation, Chemistry, and Compositions. Chem. Eur. J.. Accepted Author Manuscript. doi:10.1002/chem.202000707 which has been published in final form at http://dx.doi.org/10.1002/chem.202000707. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions." | ||||||||
| Access rights to Published version: | Restricted or Subscription Access | ||||||||
| RIOXX Funder/Project Grant: |
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