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Copper(I) and copper(II) complexes of an ethylene cross-bridged cyclam

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UNSPECIFIED (2000) Copper(I) and copper(II) complexes of an ethylene cross-bridged cyclam. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 56 (Part 1). pp. 37-39. ISSN 0108-2701

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Abstract

The preparation and crystal structures of (4,11-dibenzyl-1,4,8,11-tetraazabicyclo[6.6.2]hexadecane-kappa(4)N)copper(I) hexafluorophosphate, [Cu(C26H38N4)]PF6, and acetonitrile (4,11-dibenzyl-1,4,8,11-tetraazabicyclo[6.6.2]hexadecane-kappa(4)N)-copper(II) bis(hexafluorophosphate), [Cu(C2H3N)(C26H38N4)](PF6)(2), are described. The Cu-I ion is tetracoordinated in a very distorted tetrahedron, while the Cu-II analogue is pentacoordinated in a square pyramid.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Journal or Publication Title: ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
Publisher: MUNKSGAARD INT PUBL LTD
ISSN: 0108-2701
Date: January 2000
Volume: 56
Number: Part 1
Number of Pages: 3
Page Range: pp. 37-39
Publication Status: Published
URI: http://wrap.warwick.ac.uk/id/eprint/13650

Data sourced from Thomson Reuters' Web of Knowledge

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