A reinvestigation of the kinetics and mechanism of the reaction of 1,4,8,11-tetraazacyclotetradecane (cyclam) with [Cu(OH)(n)](2-n) ions (n=3, 4) at high pH
UNSPECIFIED (1999) A reinvestigation of the kinetics and mechanism of the reaction of 1,4,8,11-tetraazacyclotetradecane (cyclam) with [Cu(OH)(n)](2-n) ions (n=3, 4) at high pH. REVUE ROUMAINE DE CHIMIE, 44 (1). pp. 31-38. ISSN 0035-3930Full text not available from this repository.
Reinvestigation of the reaction of cyclam with Cu(II) over an extended UV wavelength range, in a base concentration range 10(-3)-10(-1) mol dm(-3), showed a more complex behavior than that previously reported. It was noticed that the rapid bimolecular binding was followed by two slower first-order processes. The reaction mechanism proposed to explain the experimental facts assumes that the complex formed during the rapid stage undergoes two slow isomerisation processes, in order to acquire its thermodynamically stable conformation found in the solid state.
|Item Type:||Journal Article|
|Subjects:||Q Science > QD Chemistry|
|Journal or Publication Title:||REVUE ROUMAINE DE CHIMIE|
|Publisher:||EDITURA ACADEMIEI ROMANE|
|Number of Pages:||8|
|Page Range:||pp. 31-38|
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