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Development of experimental techniques for parameterization of multi-scale lithium-ion battery models
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Chen, Chang-Hui, Brosa Planella, Ferran, O'Regan, Kieran, Gastol, Dominika E., Widanage, Widanalage Dhammika and Kendrick, Emma (2020) Development of experimental techniques for parameterization of multi-scale lithium-ion battery models. Journal of The Electrochemical Society, 167 (8). 080534. doi:10.1149/1945-7111/ab9050
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Official URL: http://dx.doi.org/10.1149/1945-7111/ab9050
Abstract
Presented here, is an extensive 35 parameter experimental data set of a cylindrical 21700 commercial cell (LGM50), for an electrochemical pseudo-two-dimensional (P2D) model. The experimental methodologies for tear-down and subsequent chemical, physical, electrochemical kinetics and thermodynamic analysis, and their accuracy and validity are discussed. Chemical analysis of the LGM50 cell shows that it is comprised of a NMC 811 positive electrode and bi-component Graphite-SiOx negative electrode. The thermodynamic open circuit voltages (OCV) and lithium stoichiometry in the electrode are obtained using galvanostatic intermittent titration technique (GITT) in half cell and three-electrode full cell configurations. The activation energy and exchange current coefficient through electrochemical impedance spectroscopy (EIS) measurements. Apparent diffusion coefficients are estimated using the Sand equation on the voltage transient during the current pulse; an expansion factor was applied to the bi-component negative electrode data to reflect the average change in effective surface area during lithiation. The 35 parameters are applied within a P2D model to show the fit to experimental validation LGM50 cell discharge and relaxation voltage profiles at room temperature. The accuracy and validity of the processes and the techniques in the determination of these parameters are discussed, including opportunities for further modelling and data analysis improvements.
| Item Type: | Journal Article | ||||||
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| Subjects: | Q Science > Q Science (General) Q Science > QD Chemistry T Technology > TK Electrical engineering. Electronics Nuclear engineering |
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| Divisions: | Faculty of Science, Engineering and Medicine > Engineering > WMG (Formerly the Warwick Manufacturing Group) | ||||||
| Library of Congress Subject Headings (LCSH): | Lithium ion batteries, Stoichiometry, Impedance spectroscopy | ||||||
| Journal or Publication Title: | Journal of The Electrochemical Society | ||||||
| Publisher: | Electrochemical Society, Inc. | ||||||
| ISSN: | 0013-4651 | ||||||
| Official Date: | 15 May 2020 | ||||||
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| Volume: | 167 | ||||||
| Number: | 8 | ||||||
| Article Number: | 080534 | ||||||
| DOI: | 10.1149/1945-7111/ab9050 | ||||||
| Status: | Peer Reviewed | ||||||
| Publication Status: | Published | ||||||
| Access rights to Published version: | Open Access | ||||||
| Grant number: | FIRG003 | ||||||
| RIOXX Funder/Project Grant: |
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