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Effective thermal-oxidative reclamation of waste tire rubbers for producing high-performance rubber composites
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Zhang, Yuxin, Zhang, Zhen, Wemyss, Alan M., Wan, Chaoying, Liu, Yongtao, Song, Pan and Wang, Shifeng (2020) Effective thermal-oxidative reclamation of waste tire rubbers for producing high-performance rubber composites. ACS Sustainable Chemistry & Engineering, 8 (24). pp. 9079-9087. doi:10.1021/acssuschemeng.0c02292 ISSN 2168-0485.
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WRAP-Effective-thermal-oxidative-reclamation-waste-tire-rubbers-composites-Wan-2020.pdf - Accepted Version - Requires a PDF viewer. Download (1553Kb) | Preview |
Official URL: http://dx.doi.org/10.1021/acssuschemeng.0c02292
Abstract
The disposal and accumulation of waste tire rubbers has a significant negative impact on the development of a circular economy and sustainable environment. To reuse and recycle ground tire rubber, we developed a thermal-oxidative reclamation process using a newly designed dynamic reclamation reactor. In the absence of any chemical agent, a high scission efficiency was achieved at a sol fraction of 66.53 wt% at 200 °C after 20 min from the thermal oxidation of GTR. The physical and chemical structural evolutions of GTR during the thermo-oxidation process were systemically investigated by monitoring the Mooney viscosity, sol-gel ratio, molecular weight and chemical structure changes. The reclaimed ground tire rubber containing ultrafine fillers and soluble elastomer can be easily dispersed into a natural rubber matrix. The mechanical properties and aging resistance of the modified natural rubber were enhanced with the addition of up to 40 wt% reclaimed ground tire rubber. This work demonstrates a green and up-scalable approach for reclamation and reuse of waste tire rubbers for a sustainable rubber industry.
Item Type: | Journal Article | ||||||||||||
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Subjects: | T Technology > TA Engineering (General). Civil engineering (General) T Technology > TD Environmental technology. Sanitary engineering T Technology > TE Highway engineering. Roads and pavements T Technology > TS Manufactures |
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Divisions: | Faculty of Science, Engineering and Medicine > Engineering > WMG (Formerly the Warwick Manufacturing Group) | ||||||||||||
Library of Congress Subject Headings (LCSH): | Tires, Waste tires, Crumb rubber , Crumb rubber -- Heat treatment, Nanocomposites (Materials) , Rubber -- Industrial applications | ||||||||||||
Journal or Publication Title: | ACS Sustainable Chemistry & Engineering | ||||||||||||
Publisher: | American Chemical Society | ||||||||||||
ISSN: | 2168-0485 | ||||||||||||
Official Date: | 22 June 2020 | ||||||||||||
Dates: |
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Volume: | 8 | ||||||||||||
Number: | 24 | ||||||||||||
Page Range: | pp. 9079-9087 | ||||||||||||
DOI: | 10.1021/acssuschemeng.0c02292 | ||||||||||||
Status: | Peer Reviewed | ||||||||||||
Publication Status: | Published | ||||||||||||
Reuse Statement (publisher, data, author rights): | “This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Sustainable Chemistry & Engineering, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [insert ACS Articles on Request author-directed link to Published Work, see http://pubs.acs.org/page/policy/articlesonrequest/index.html].” | ||||||||||||
Access rights to Published version: | Restricted or Subscription Access | ||||||||||||
Copyright Holders: | © 2020 American Chemical Society | ||||||||||||
Date of first compliant deposit: | 29 May 2020 | ||||||||||||
Date of first compliant Open Access: | 22 May 2021 | ||||||||||||
RIOXX Funder/Project Grant: |
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