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Unimolecular ion dissociation and laser-induced coalescence of hydrogenated fullerenes

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UNSPECIFIED (2000) Unimolecular ion dissociation and laser-induced coalescence of hydrogenated fullerenes. INTERNATIONAL JOURNAL OF MASS SPECTROMETRY, 196 (Sp. Iss. SI). pp. 599-607. ISSN 1387-3806.

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Abstract

The ion-fragmentation behaviour of hydrogenated fullerenes has been investigated by tandem mass spectrometry applying sector instrumentation. In addition to the expected loss of hydrogen, unimolecular decay reactions are observed featuring cage rupture by the loss of hydrocarbon moieties. The findings are discussed in comparison with the behaviour of other fullerene derivatives. The gas-phase coalescence reactivity of C60H36 has been studied utilising laser desorption/ionization time-of-flight mass spectrometry. In contrast to pure fullerenes and certain organic fullerene derivatives, hydrogenated fullerenes do not readily undergo laser-induced fusion reactions. (C) 2000 Elsevier Science B.V.

Item Type: Journal Article
Subjects: Q Science > QC Physics
Journal or Publication Title: INTERNATIONAL JOURNAL OF MASS SPECTROMETRY
Publisher: ELSEVIER SCIENCE BV
ISSN: 1387-3806
Official Date: 21 January 2000
Dates:
DateEvent
21 January 2000UNSPECIFIED
Volume: 196
Number: Sp. Iss. SI
Number of Pages: 9
Page Range: pp. 599-607
Publication Status: Published

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