The Library
Orthogonal cationic and radical RAFT polymerizations to prepare bottlebrush polymers
Tools
Tanaka, Joji, Häkkinen, Satu, Boeck, Parker T., Cong, Yidan, Perrier, Sébastien, Sheiko, Sergei S. and You, Wei (2020) Orthogonal cationic and radical RAFT polymerizations to prepare bottlebrush polymers. Angewandte Chemie International Edition, 59 (18). pp. 7203-7208. doi:10.1002/anie.202000700 ISSN 1433-7851.
|
PDF
WRAP-orthogonal-cationic-radical-RAFT-polymerizations-prepare-bottlebrush-polymers-Perrier-2020.pdf - Accepted Version - Requires a PDF viewer. Download (1762Kb) | Preview |
Official URL: http://dx.doi.org/10.1002/anie.202000700
Abstract
An orthogonal combination of cationic and radical RAFT polymerizations is used to synthesize bottlebrush polymers using two distinct RAFT agents. Selective consumption of the first RAFT agent is used to control the cationic RAFT polymerization of a vinyl ether monomer bearing a secondary dormant RAFT agent, which subsequently allows side‐chain polymers to be grafted from the pendant RAFT agent by a radical‐mediated RAFT polymerization of a different monomer, thus completing the synthesis of bottlebrush polymers. The high efficiency and selectivity of the cationic and radical RAFT polymerizations allow both polymerizations to be conducted in one‐pot tandem without intermediate purification.
Item Type: | Journal Article | ||||||||
---|---|---|---|---|---|---|---|---|---|
Alternative Title: | |||||||||
Subjects: | Q Science > QD Chemistry | ||||||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||||||
Library of Congress Subject Headings (LCSH): | Polymerization, Polymers, Copolymers -- Synthesis, Nanostructures -- Therapeutic use -- Administration, Polymeric drug delivery systems | ||||||||
Journal or Publication Title: | Angewandte Chemie International Edition | ||||||||
Publisher: | Wiley - V C H Verlag GmbH & Co. KGaA | ||||||||
ISSN: | 1433-7851 | ||||||||
Official Date: | 20 April 2020 | ||||||||
Dates: |
|
||||||||
Volume: | 59 | ||||||||
Number: | 18 | ||||||||
Page Range: | pp. 7203-7208 | ||||||||
DOI: | 10.1002/anie.202000700 | ||||||||
Status: | Peer Reviewed | ||||||||
Publication Status: | Published | ||||||||
Reuse Statement (publisher, data, author rights): | This is the peer reviewed version of the following article: J. Tanaka, S. Häkkinen, P. T. Boeck, Y. Cong, S. Perrier, S. S. Sheiko, W. You, Angew. Chem. Int. Ed. 2020 , 59 , 7203., which has been published in final form at https://doi.org/10.1002/anie.202000700. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. | ||||||||
Access rights to Published version: | Restricted or Subscription Access | ||||||||
Date of first compliant deposit: | 18 June 2020 | ||||||||
Date of first compliant Open Access: | 15 February 2021 | ||||||||
RIOXX Funder/Project Grant: |
|
Request changes or add full text files to a record
Repository staff actions (login required)
View Item |
Downloads
Downloads per month over past year