Following local adsorption sites through a surface chemical reaction: CH3SH on Cu(111)
UNSPECIFIED. (2000) Following local adsorption sites through a surface chemical reaction: CH3SH on Cu(111). PHYSICAL REVIEW LETTERS, 84 (1). pp. 119-122. ISSN 0031-9007Full text not available from this repository.
Studying the interaction of CH3SH, methanethiol, with Cu(111) as a model system, we demonstrate the ability of chemical-shift normal incidence x-ray standing wave field measurements to identify the local adsorption geometries of coadsorbed reaction products at different temperatures, a technical problem of broad chemical significance. In the present case the local geometries of four distinct S-containing adsorbate species (intact CH3SH, two thiolate (CH3S-) reaction intermediates and atomic S) are determined.
|Item Type:||Journal Article|
|Subjects:||Q Science > QC Physics|
|Journal or Publication Title:||PHYSICAL REVIEW LETTERS|
|Publisher:||AMERICAN PHYSICAL SOC|
|Date:||3 January 2000|
|Number of Pages:||4|
|Page Range:||pp. 119-122|
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