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Following local adsorption sites through a surface chemical reaction: CH3SH on Cu(111)

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UNSPECIFIED (2000) Following local adsorption sites through a surface chemical reaction: CH3SH on Cu(111). PHYSICAL REVIEW LETTERS, 84 (1). pp. 119-122. ISSN 0031-9007.

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Abstract

Studying the interaction of CH3SH, methanethiol, with Cu(111) as a model system, we demonstrate the ability of chemical-shift normal incidence x-ray standing wave field measurements to identify the local adsorption geometries of coadsorbed reaction products at different temperatures, a technical problem of broad chemical significance. In the present case the local geometries of four distinct S-containing adsorbate species (intact CH3SH, two thiolate (CH3S-) reaction intermediates and atomic S) are determined.

Item Type: Journal Article
Subjects: Q Science > QC Physics
Journal or Publication Title: PHYSICAL REVIEW LETTERS
Publisher: AMERICAN PHYSICAL SOC
ISSN: 0031-9007
Official Date: 3 January 2000
Dates:
DateEvent
3 January 2000UNSPECIFIED
Volume: 84
Number: 1
Number of Pages: 4
Page Range: pp. 119-122
Publication Status: Published

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