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Following local adsorption sites through a surface chemical reaction: CH3SH on Cu(111)
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UNSPECIFIED (2000) Following local adsorption sites through a surface chemical reaction: CH3SH on Cu(111). PHYSICAL REVIEW LETTERS, 84 (1). pp. 119-122. ISSN 0031-9007.
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Abstract
Studying the interaction of CH3SH, methanethiol, with Cu(111) as a model system, we demonstrate the ability of chemical-shift normal incidence x-ray standing wave field measurements to identify the local adsorption geometries of coadsorbed reaction products at different temperatures, a technical problem of broad chemical significance. In the present case the local geometries of four distinct S-containing adsorbate species (intact CH3SH, two thiolate (CH3S-) reaction intermediates and atomic S) are determined.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Subjects: | Q Science > QC Physics | ||||
| Journal or Publication Title: | PHYSICAL REVIEW LETTERS | ||||
| Publisher: | AMERICAN PHYSICAL SOC | ||||
| ISSN: | 0031-9007 | ||||
| Official Date: | 3 January 2000 | ||||
| Dates: |
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| Volume: | 84 | ||||
| Number: | 1 | ||||
| Number of Pages: | 4 | ||||
| Page Range: | pp. 119-122 | ||||
| Publication Status: | Published |
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