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Efficient room temperature copper(I) mediated 5-endo radical cyclisations
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UNSPECIFIED (1999) Efficient room temperature copper(I) mediated 5-endo radical cyclisations. TETRAHEDRON LETTERS, 40 (49). pp. 8619-8623. ISSN 0040-4039
Full text not available from this repository.Abstract
Reaction of bromo-enamides with catalytic Cu(Me-6-trien)Br at room temperature furnishes regioisomeric mixtures of unsaturated pyrrolidinones in a highly efficient manner via an initial 5-endo radical cyclisation reaction followed by an oxidation and elimination of H+. Bromo-enamide 3f furnishes the beta-lactam via a 4-exo cyclisation pathway. (C) 1999 Elsevier Science Ltd. All rights reserved.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | TETRAHEDRON LETTERS |
| Publisher: | PERGAMON-ELSEVIER SCIENCE LTD |
| ISSN: | 0040-4039 |
| Date: | 3 December 1999 |
| Volume: | 40 |
| Number: | 49 |
| Number of Pages: | 5 |
| Page Range: | pp. 8619-8623 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/14008 |
Data sourced from Thomson Reuters' Web of Knowledge
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