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Linear and unanticipated second-order nonlinear optical properties of benzylic amide [2]Catenane thin films: Evidence of partial rotation of the interlocked molecular rings in the solid state
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UNSPECIFIED (1999) Linear and unanticipated second-order nonlinear optical properties of benzylic amide [2]Catenane thin films: Evidence of partial rotation of the interlocked molecular rings in the solid state. ADVANCED MATERIALS, 11 (15). 1303-+. ISSN 0935-9648.
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Abstract
Communication: Control of the rotation of the interlocked rings in catenanes through external stimuli is key to the development of these molecules as components in nanoscale devices such as molecular switches. shuttles, and information storage systems. Here the Linear and unanticipated second-order nonlinear optical properties of vacuum-evaporated thin films of a benzylic amide [2]catenane, consisting of two identical 26-membered macrocyclic rings, are reported. Electro-optic measurements provide evidence that the catenane rings rotate at least partially in the solid state on application on an external, time-dependent electric field.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Subjects: | Q Science > QD Chemistry T Technology T Technology > TA Engineering (General). Civil engineering (General) Q Science > QC Physics |
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| Journal or Publication Title: | ADVANCED MATERIALS | ||||
| Publisher: | WILEY-V C H VERLAG GMBH | ||||
| ISSN: | 0935-9648 | ||||
| Official Date: | 20 October 1999 | ||||
| Dates: |
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| Volume: | 11 | ||||
| Number: | 15 | ||||
| Number of Pages: | 5 | ||||
| Page Range: | 1303-+ | ||||
| Publication Status: | Published |
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