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Data for Electric field-controlled synthesis and characterisation of single metal-organic-framework (MOF) nanoparticles
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Morris, Peter D. J., McPherson, Ian J., Edwards, Martin A., Kashtiban, Reza J., Walton, Richard I. and Unwin, Patrick R. (2020) Data for Electric field-controlled synthesis and characterisation of single metal-organic-framework (MOF) nanoparticles. [Dataset]
Archive (ZIP) (Zip archive)
HKUSTData.zip - Published Version Available under License Creative Commons Attribution 4.0. Download (1559Mb) |
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Plain Text (Readme file)
Details.txt - Published Version Available under License Creative Commons Attribution 4.0. Download (274b) |
Abstract
Achieving control over the size distribution of metal organic framework (MOF) nanoparticles is key to biomedical applications and seeding techniques. Electrochemical control over the nanoparticle synthesis of the MOF, HKUST‐1, is achieved using a nanopipette injection method to locally mix Cu 2+ salt precursor and benzene tricarboxylate (BTC 3‐ ) ligand reagents, form MOF nanocrystals, and collect and characterise them on a TEM grid. In situ analysis of the size and translocation frequency of HKUST‐1 nanoparticles is demonstrated, using the nanopipette to detect resistive pulses as nanoparticles form. Complementary modelling of mass transport in the electric field, enables particle size to be estimated and explains the feasibility of particular reaction conditions, including inhibitory effects of excess BTC 3‐ . These new methods should be applicable to a variety of MOFs, and scaling up synthesis possible via arrays of nanoscale reaction centres, for example using nanopore membranes.
Item Type: | Dataset | ||||||
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Subjects: | Q Science > QD Chemistry | ||||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||||
Type of Data: | Experimental data | ||||||
Library of Congress Subject Headings (LCSH): | Electrochemistry, Metal-organic frameworks, Nanoparticles | ||||||
Publisher: | University of Warwick, Department of Chemistry | ||||||
Official Date: | 7 June 2020 | ||||||
Dates: |
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Status: | Not Peer Reviewed | ||||||
Publication Status: | Published | ||||||
Media of Output (format): | .txt .pdf .png .mat .m | ||||||
Access rights to Published version: | Open Access (Creative Commons) | ||||||
Copyright Holders: | University of Warwick | ||||||
Description: | Data record consists of a zip archive, containing 8 subfolders organised according to data contained, and accompanying readme file. Data is electrochemical transient data in ASCII Text File. |
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Date of first compliant deposit: | 17 August 2020 | ||||||
Date of first compliant Open Access: | 17 August 2020 | ||||||
RIOXX Funder/Project Grant: |
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