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The structure of [GaBr3(Me-3[9]aneN(3))]: The first example of a six co-ordinate gallium(III) bromide complex
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UNSPECIFIED (1999) The structure of [GaBr3(Me-3[9]aneN(3))]: The first example of a six co-ordinate gallium(III) bromide complex. MAIN GROUP METAL CHEMISTRY, 22 (8). pp. 515-518. ISSN 0334-7575
Full text not available from this repository.Abstract
Reaction of equimolar quantities of gallium(lll) bromide and 1,4,7-trimethyl-1,4,7-triazacyclononane (Me-3[9]aneN(3)) in acetonitrile gives the neutral adduct [GaBr3(Me-3[9]aneN(3))]. A crystal structure determination (X-ray diffraction) confirms a half-sandwich topology in which the six cc-ordinate metal centre adopts the expected fac-octahedral geometry, following eta(3) N-donor co-ordination of the azamacrocycle.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | MAIN GROUP METAL CHEMISTRY |
| Publisher: | FREUND PUBLISHING HOUSE LTD |
| ISSN: | 0334-7575 |
| Date: | August 1999 |
| Volume: | 22 |
| Number: | 8 |
| Number of Pages: | 4 |
| Page Range: | pp. 515-518 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/14098 |
Data sourced from Thomson Reuters' Web of Knowledge
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