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Hydrogen bond template-directed polymerization of protected 5 '-acryloylnucleosides
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UNSPECIFIED (1999) Hydrogen bond template-directed polymerization of protected 5 '-acryloylnucleosides. MACROMOLECULES, 32 (20). pp. 6560-6564.
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Abstract
Poly(5'-acryloyluridine) has been shown to act as a template in the radical polymerization of the complementary 5'-acryloyladenosine in the presence of the noncomplementary 5'-acryloyluridine. The template was synthesized by polymerizing 5'-acryloyluridine using AIBN as the initiator. The 5'-acryloylnucleosides were synthesized by regiospecific acylation of adenosine and uridine at the 5'-position using the enzyme Candida antarctica lipase 435 (CAL 435). The remaining hydroxyl groups were protected as silyl ethers to increase the solubility in nonpolar solvents.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Subjects: | Q Science > QD Chemistry | ||||
| Journal or Publication Title: | MACROMOLECULES | ||||
| Publisher: | AMER CHEMICAL SOC | ||||
| ISSN: | 0024-9297 | ||||
| Official Date: | 5 October 1999 | ||||
| Dates: |
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| Volume: | 32 | ||||
| Number: | 20 | ||||
| Number of Pages: | 5 | ||||
| Page Range: | pp. 6560-6564 | ||||
| Publication Status: | Published |
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