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Hydrogen bond template-directed polymerization of protected 5 '-acryloylnucleosides

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UNSPECIFIED. (1999) Hydrogen bond template-directed polymerization of protected 5 '-acryloylnucleosides. MACROMOLECULES, 32 (20). pp. 6560-6564. ISSN 0024-9297

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Abstract

Poly(5'-acryloyluridine) has been shown to act as a template in the radical polymerization of the complementary 5'-acryloyladenosine in the presence of the noncomplementary 5'-acryloyluridine. The template was synthesized by polymerizing 5'-acryloyluridine using AIBN as the initiator. The 5'-acryloylnucleosides were synthesized by regiospecific acylation of adenosine and uridine at the 5'-position using the enzyme Candida antarctica lipase 435 (CAL 435). The remaining hydroxyl groups were protected as silyl ethers to increase the solubility in nonpolar solvents.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Journal or Publication Title: MACROMOLECULES
Publisher: AMER CHEMICAL SOC
ISSN: 0024-9297
Date: 5 October 1999
Volume: 32
Number: 20
Number of Pages: 5
Page Range: pp. 6560-6564
Publication Status: Published
URI: http://wrap.warwick.ac.uk/id/eprint/14116

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