The Library
N,N '-Unsubstituted amidinato metallacycle complexes of Group 13 metal alkyls: the crystal structure of trimeric [{Me2Al(mu-HNCPhNH)}(3)]
Tools
Tools
Tools
UNSPECIFIED (1999) N,N '-Unsubstituted amidinato metallacycle complexes of Group 13 metal alkyls: the crystal structure of trimeric [{Me2Al(mu-HNCPhNH)}(3)]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 586 (2). pp. 138-144. ISSN 0022-328X
Full text not available from this repository.Abstract
The amidinato complexes [Me2ML] (L = HNCPhNH, M = Al, Ga, In; L = (HNCBuNH)-N-t, M = Ga) result from the reaction of the trialkylmetal with an equimolar amount of the amidine. MS data indicate that the complexes exist as dimers or trimers in the gas phase. X-ray crystallographic studies on [(Me2Al(mu-KNCPhNH)}(3)] (1) reveal a novel trimeric structure in the solid state, with bridging benzamidinato ligands, and a 12-membered metallacycle. Reaction of InMe3 with two moles of benzamidine yields a cyclic imidoylamidinato derivative with a six-membered [InNCNCN] ring. (C) 1999 Elsevier Science S.A. All rights reserved.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | JOURNAL OF ORGANOMETALLIC CHEMISTRY |
| Publisher: | ELSEVIER SCIENCE SA |
| ISSN: | 0022-328X |
| Date: | 5 September 1999 |
| Volume: | 586 |
| Number: | 2 |
| Number of Pages: | 7 |
| Page Range: | pp. 138-144 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/14188 |
Data sourced from Thomson Reuters' Web of Knowledge
Actions (login required)
 |
View Item |
