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Structure and reactions of a metallacyclic complex containing a remarkably long uranium-carbon bond
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UNSPECIFIED (1999) Structure and reactions of a metallacyclic complex containing a remarkably long uranium-carbon bond. CHEMICAL COMMUNICATIONS (17). pp. 1701-1702. ISSN 1359-7345.
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Abstract
The intramolecular metalation of a beta-silyl methyl group in [U{N(CH2CH2NSiMe2But)(3)}(CH2Ph)] occurs rapidly, despite the conformational demands of the triamidoamine ligand, to produce a highly strained metallacycle (U-C ca. 2.75 Angstrom); this complex reacts cleanly with a range of carbon and other acids to give, for example, an alkynyl with a bent (156 degrees) U-C=C unit.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | CHEMICAL COMMUNICATIONS | ||||
Publisher: | ROYAL SOC CHEMISTRY | ||||
ISSN: | 1359-7345 | ||||
Official Date: | 7 September 1999 | ||||
Dates: |
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Number: | 17 | ||||
Number of Pages: | 2 | ||||
Page Range: | pp. 1701-1702 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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