The Library
Structure and reactions of a metallacyclic complex containing a remarkably long uranium-carbon bond
Tools
Tools
Tools
UNSPECIFIED (1999) Structure and reactions of a metallacyclic complex containing a remarkably long uranium-carbon bond. CHEMICAL COMMUNICATIONS (17). pp. 1701-1702. ISSN 1359-7345
Full text not available from this repository.Abstract
The intramolecular metalation of a beta-silyl methyl group in [U{N(CH2CH2NSiMe2But)(3)}(CH2Ph)] occurs rapidly, despite the conformational demands of the triamidoamine ligand, to produce a highly strained metallacycle (U-C ca. 2.75 Angstrom); this complex reacts cleanly with a range of carbon and other acids to give, for example, an alkynyl with a bent (156 degrees) U-C=C unit.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | CHEMICAL COMMUNICATIONS |
| Publisher: | ROYAL SOC CHEMISTRY |
| ISSN: | 1359-7345 |
| Date: | 7 September 1999 |
| Number: | 17 |
| Number of Pages: | 2 |
| Page Range: | pp. 1701-1702 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/14270 |
Data sourced from Thomson Reuters' Web of Knowledge
Actions (login required)
 |
View Item |
