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Schiff-base chemistry of niobium: unexpected products of radical elimination and diastereoselective addition
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UNSPECIFIED (1999) Schiff-base chemistry of niobium: unexpected products of radical elimination and diastereoselective addition. [Journal Item]
Full text not available from this repository.Abstract
The two main products from the reaction of a chiral Schiff-base proligand H2L with [Nb-IV(NEt2)(4)] are the amidoimido species [LNbV(NEt)(VEt2)] and the highly unusual [L'Nb-V(NEt2)(2)] in which a 1-ethylaminoethyl radical has undergone highly diastereoselective addition to one of the coordinated imine groups.
| Item Type: | Journal Item |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | NEW JOURNAL OF CHEMISTRY |
| Publisher: | GAUTHIER-VILLARS/EDITIONS ELSEVIER |
| ISSN: | 1144-0546 |
| Date: | August 1999 |
| Volume: | 23 |
| Number: | 8 |
| Number of Pages: | 3 |
| Page Range: | pp. 815-817 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/14272 |
Data sourced from Thomson Reuters' Web of Knowledge
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