Schiff-base chemistry of niobium: unexpected products of radical elimination and diastereoselective addition
UNSPECIFIED (1999) Schiff-base chemistry of niobium: unexpected products of radical elimination and diastereoselective addition. [Journal Item]Full text not available from this repository.
The two main products from the reaction of a chiral Schiff-base proligand H2L with [Nb-IV(NEt2)(4)] are the amidoimido species [LNbV(NEt)(VEt2)] and the highly unusual [L'Nb-V(NEt2)(2)] in which a 1-ethylaminoethyl radical has undergone highly diastereoselective addition to one of the coordinated imine groups.
|Item Type:||Journal Item|
|Subjects:||Q Science > QD Chemistry|
|Journal or Publication Title:||NEW JOURNAL OF CHEMISTRY|
|Number of Pages:||3|
|Page Range:||pp. 815-817|
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