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An open chain trinuclear titanium(IV) isopropoxide species formed with the tridentate ligand cis,cis-cyclohexane-1,3,5-trialkoxide [C6H9O3](3-). Crystal structure of [{Ti(OPri)(3)}(2){mu-Ti(C6H9O3-O-1,O-5)(2)}]
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UNSPECIFIED (1999) An open chain trinuclear titanium(IV) isopropoxide species formed with the tridentate ligand cis,cis-cyclohexane-1,3,5-trialkoxide [C6H9O3](3-). Crystal structure of [{Ti(OPri)(3)}(2){mu-Ti(C6H9O3-O-1,O-5)(2)}]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS (16). pp. 2647-2649. ISSN 0300-9246
Full text not available from this repository.Abstract
Reaction of titanium(IV) tetraisopropoxide with cis,cis-cyclohexane-1,3,5-triol [C6H9(OH)(3), H3L] affords the novel trinuclear titanium(IV) alkoxide species [{Ti(OPri)(3)}(2){mu-Ti(C6H9O3-O-1,O-5)(2)}] {L = [C6H9O3](3-)} which possesses a unique open-chain V-shaped arrangement of three titanium atoms, with the central 6-co-ordinate Ti atom bonded to two tridentate L groups, and with each of the two terminal Ti atoms 5-co-ordinate, forming bonds to three non-bridging isopropoxide groups, and to two bridging oxygen atoms, one from each of the two ligands L.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS |
| Publisher: | ROYAL SOC CHEMISTRY |
| ISSN: | 0300-9246 |
| Date: | 21 August 1999 |
| Number: | 16 |
| Number of Pages: | 3 |
| Page Range: | pp. 2647-2649 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/14276 |
Data sourced from Thomson Reuters' Web of Knowledge
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