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A sodium-ion battery exploiting layered oxide cathode, graphite anode and glyme-based electrolyte

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Hasa, Ivana, Dou, Xinwei, Buchholz, Daniel, Shao-Horn, Yang, Hassoun, Jusef, Passerini, Stefano and Scrosati, Bruno (2016) A sodium-ion battery exploiting layered oxide cathode, graphite anode and glyme-based electrolyte. Journal of Power Sources, 310 . pp. 26-31. doi:10.1016/j.jpowsour.2016.01.082

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Official URL: http://dx.doi.org/10.1016/j.jpowsour.2016.01.082

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Abstract

Room-temperature rechargeable sodium-ion batteries (SIBs), in view of the large availability and low cost of sodium raw materials, represent an important class of electrochemical systems suitable for application in large-scale energy storage. In this work, we report a novel, high power SIB formed by coupling the layered P2-Na0.7CoO2 cathode with the graphite anode in an optimized ether-based electrolyte. The study firstly addresses the electrochemical optimization of the two electrode materials and then the realization and characterization of the novel SIB based on their combination. The cell represents an original sodium rocking chair battery obtained combining the intercalation/de-intercalation processes of sodium within the cathode and anode layers. We show herein that this battery, favored by suitable electrode/electrolyte combination, offers unique performance in terms of cycle life, efficiency and, especially, power capability.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
T Technology > TK Electrical engineering. Electronics Nuclear engineering
Divisions: Faculty of Science > WMG (Formerly the Warwick Manufacturing Group)
Library of Congress Subject Headings (LCSH): Sodium ion batteries, Fuel cells, Energy storage, Electric batteries -- Electrodes, Graphite composites
Journal or Publication Title: Journal of Power Sources
Publisher: Elsevier S.A.
ISSN: 0378-7753
Official Date: 1 April 2016
Dates:
DateEvent
1 April 2016Published
10 February 2016Available
22 January 2016Accepted
Date of first compliant deposit: 23 October 2020
Volume: 310
Page Range: pp. 26-31
DOI: 10.1016/j.jpowsour.2016.01.082
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Restricted or Subscription Access
RIOXX Funder/Project Grant:
Project/Grant IDRIOXX Funder NameFunder ID
608621Seventh Framework Programmehttp://dx.doi.org/10.13039/100011102

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