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Electrical characterization of thermally activated defects in n-type float-zone silicon

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Zhu, Yan, Rougieux, Fiacre, Grant, Nicholas E., de Guzman, Joyce Ann T., Murphy, John D., Markevich, Vladimir P., Coletti, Gianluca, Peaker, Anthony R. and Hameiri, Ziv (2021) Electrical characterization of thermally activated defects in n-type float-zone silicon. IEEE Journal of Photovoltaics, 11 (1). pp. 26-35. doi:10.1109/JPHOTOV.2020.3031382

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Official URL: https://doi.org/10.1109/JPHOTOV.2020.3031382

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Abstract

Float-zone (FZ) silicon is usually assumed to be bulk defect-lean and stable. However, recent studies have revealed that detrimental defects can be thermally activated in FZ silicon wafers and lead to a reduction of carrier lifetime by up to two orders of magnitude. A robust methodology which combines different characterization techniques and passivation schemes is used to provide new insight into the origin of degradation of 1 Ω·cm n-type phosphorus doped FZ silicon (with nitrogen doping during growth) after annealing at 500 °C. Carrier lifetime and photoluminescence experiments are first performed with temporary room temperature surface passivation which minimizes lifetime changes which can occur during passivation processes involving thermal treatments. Temperature- and injection-dependent lifetime spectroscopy is then performed with a more stable passivation scheme, with the same samples finally being studied by deep level transient spectroscopy (DLTS). Although five defect levels are found with DLTS, detailed analysis of injection-dependent lifetime data reveals that the most detrimental defect levels could arise from just two independent single-level defects or from one two-level defect. The defect parameters for these two possible scenarios are extracted and discussed.

Item Type: Journal Article
Alternative Title:
Subjects: Q Science > QC Physics
Divisions: Faculty of Science, Engineering and Medicine > Engineering > Engineering
Library of Congress Subject Headings (LCSH): Silicon carbide -- Electric properties , Deep level transient spectroscopy , Photovoltaic effect
Journal or Publication Title: IEEE Journal of Photovoltaics
Publisher: IEEE
ISSN: 2156-3381
Official Date: January 2021
Dates:
DateEvent
January 2021Published
29 October 2020Available
9 October 2020Accepted
Volume: 11
Number: 1
Page Range: pp. 26-35
DOI: 10.1109/JPHOTOV.2020.3031382
Status: Peer Reviewed
Publication Status: Published
Reuse Statement (publisher, data, author rights): © 2020 IEEE. Personal use of this material is permitted. Permission from IEEE must be obtained for all other uses, in any current or future media, including reprinting/republishing this material for advertising or promotional purposes, creating new collective works, for resale or redistribution to servers or lists, or reuse of any copyrighted component of this work in other works.
Access rights to Published version: Open Access
RIOXX Funder/Project Grant:
Project/Grant IDRIOXX Funder NameFunder ID
EP/M024911/1 [EPSRC] Engineering and Physical Sciences Research Councilhttp://dx.doi.org/10.13039/501100000266
EP/J017361/1[EPSRC] Engineering and Physical Sciences Research Councilhttp://dx.doi.org/10.13039/501100000266
EP/J01768X/2[EPSRC] Engineering and Physical Sciences Research Councilhttp://dx.doi.org/10.13039/501100000266
UNSPECIFIEDAustralian Centre for Advanced Photovoltaicshttp://dx.doi.org/10.13039/100012030
UNSPECIFIEDAustralian Renewable Energy Agencyhttp://dx.doi.org/10.13039/501100005105
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