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Phase development in La2O3 doped Al2O3 : TiO2 ceramic membranes

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UNSPECIFIED (1999) Phase development in La2O3 doped Al2O3 : TiO2 ceramic membranes. JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 19 (10). pp. 1847-1857. ISSN 0955-2219

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Abstract

The phase development of sol derived diphasic Al2O3:TiO2 membranes doped with La2O3 is described together with their pore structure and microstructure. These nanostructrual membranes have been characterised using Al-27 MAS-NMR, TEM, BET, XRD and thermal analysis in an attempt to derive a comprehensive description. The membrane materials have been subjected to heat treatments ranging from 275 degrees C to 1200 degrees C in air. Doping the diphasic membrane has been shown to increase the transformation temperature of the low temperature phases (gamma-alumina and anatase) by as much as 200 degrees C. There is indication that La2O3 doping also retards the reorganisation of Al in the gamma-alumina phase preventing it from forming other intermediate aluminas. (C) 1999 Published by Elsevier Science Limited. All rights reserved.

Item Type: Journal Article
Subjects: T Technology > TP Chemical technology
Journal or Publication Title: JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
Publisher: ELSEVIER SCI LTD
ISSN: 0955-2219
Date: 1999
Volume: 19
Number: 10
Number of Pages: 11
Page Range: pp. 1847-1857
Publication Status: Published
URI: http://wrap.warwick.ac.uk/id/eprint/14347

Data sourced from Thomson Reuters' Web of Knowledge

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