UNSPECIFIED (1999) Tris (2-pyridylmethyl)triazacyclododecane complexes of Fe-II and Cu-II. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 55 (Part 6). pp. 886-889. ISSN 0108-2701

Full text not available from this repository.

Abstract

The title complexes, [1,5,9-tris(2-pyridylmethyl)1,5,9- triazacyclododecane-kappa(3)N] iron(II) tetrachloroferrate, [Fe(C27H36N6)][FeCl4], and [1,5,9-tris(2-pyridylmethyl)-1,5,9-triazacyclododecane-kappa(3)N]copper(III) bis(hexafluorophosphate) acetonitrile hemisolvate, [Cu(C27H36N6)](PF6)(2). 0.5CH(3)CN, differ significantly in their conformations. The iron complex is near-octahedral with Fe-N distances of 2.257 (5) (ring) and 2.226(5)Angstrom (pyridine), and fused chelate rings predominately in the boat form. The copper complex is tetragonally distorted, with four shorter and two longer Cu-N bonds [2.049(6)-2.199(7) and 2.280 (6)-2.473 (7) Angstrom, respectively]; its chelate rings are disordered in boat, chair and skew forms.

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry
Journal or Publication Title:	ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
Publisher:	MUNKSGAARD INT PUBL LTD
ISSN:	0108-2701
Date:	15 June 1999
Volume:	55
Number:	Part 6
Number of Pages:	4
Page Range:	pp. 886-889
Publication Status:	Published
URI:	http://wrap.warwick.ac.uk/id/eprint/14398

Data sourced from Thomson Reuters' Web of Knowledge

Request changes to a record

Actions (login required)

View Item