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Adsorption site and orientation of pyridine on Cu{110} determined by photoelectron diffraction

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UNSPECIFIED (1999) Adsorption site and orientation of pyridine on Cu{110} determined by photoelectron diffraction. JOURNAL OF CHEMICAL PHYSICS, 110 (19). pp. 9666-9672. ISSN 0021-9606

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Abstract

The local adsorption geometry of pyridine on Cu{110} has been determined quantitatively using photoelectron diffraction in the scanned-energy mode. At high coverages the molecule adsorbs nearly atop a Cu atom in the close-packed rows with a N-Cu bond length of 2.00 Angstrom. Moreover, the Cu-N axis and the molecular (C-2) axis are inclined by 8 degrees and 20 degrees, respectively, to the surface normal. The result shows that not only the adsorption site of the emitter (in this case the N atom) but also the position of relatively light scatterers (the C atoms) can be determined by photoelectron diffraction. (C) 1999 American Institute of Physics. [S0021-9606(99)70119-4].

Item Type: Journal Article
Subjects: Q Science > QC Physics
Journal or Publication Title: JOURNAL OF CHEMICAL PHYSICS
Publisher: AMER INST PHYSICS
ISSN: 0021-9606
Date: 15 May 1999
Volume: 110
Number: 19
Number of Pages: 7
Page Range: pp. 9666-9672
Publication Status: Published
URI: http://wrap.warwick.ac.uk/id/eprint/14533

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