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Data for Cu(III)–bis-thiolato complex forms an unusual mono-thiolato Cu(III)–peroxido adduct
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Donnelly, Jane M., Lermyte, Frederik, Wolny, Juliusz A., Walker, M., Breeze, B. G., Needham, Russell J., Müller, C. S., O'Connor, Peter B., Schünemann, Volker, Collingwood, Joanna F. and Sadler, Peter J. (2020) Data for Cu(III)–bis-thiolato complex forms an unusual mono-thiolato Cu(III)–peroxido adduct. [Dataset]
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Abstract
The novel stable complex [bis(toluene-3,4-dithiolato)copper(III)][NEt3H] has been synthesised and characterised as a square-planar Cu(III) complex by X-ray photoelectron spectroscopy, cyclic voltammetry and DFT calculations. Intriguingly, when fragmented in FTICR-MS, an unusual [(toluene-3,4-dithiolate)Cu(III)(peroxide)]- complex formed by reaction with oxygen. Natural 1,2-dithiolenes known to bind molybdenum might stabilise Cu(III) in vivo.
| Item Type: | Dataset | ||||||||||||||||||||||||||||||||||||
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| Subjects: | Q Science > QD Chemistry | ||||||||||||||||||||||||||||||||||||
| Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||||||||||||||||||||||||||||||||||
| Type of Data: | Experimental data | ||||||||||||||||||||||||||||||||||||
| Library of Congress Subject Headings (LCSH): | Copper enzymes -- Synthesis, Ligands (Biochemistry), Thiolates | ||||||||||||||||||||||||||||||||||||
| Publisher: | University of Warwick, Department of Chemistry | ||||||||||||||||||||||||||||||||||||
| Official Date: | 14 December 2020 | ||||||||||||||||||||||||||||||||||||
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| Status: | Not Peer Reviewed | ||||||||||||||||||||||||||||||||||||
| Publication Status: | Published | ||||||||||||||||||||||||||||||||||||
| Media of Output (format): | .xlsx | ||||||||||||||||||||||||||||||||||||
| Access rights to Published version: | Open Access (Creative Commons) | ||||||||||||||||||||||||||||||||||||
| Copyright Holders: | University of Warwick | ||||||||||||||||||||||||||||||||||||
| Description: | Data record consists of two excel sheets. |
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| Date of first compliant deposit: | 11 December 2020 | ||||||||||||||||||||||||||||||||||||
| Date of first compliant Open Access: | 4 January 2021 | ||||||||||||||||||||||||||||||||||||
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