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Stereoselectivity in amidyl radical cyclisations: Alkyl mode cyclisations
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UNSPECIFIED (1999) Stereoselectivity in amidyl radical cyclisations: Alkyl mode cyclisations. SYNLETT (4). pp. 444-446. ISSN 0936-5214
Full text not available from this repository.Abstract
Amidyl radicals 2 generated from tributylstannane mediated homolysis of O-benzoyl hydroxamic acid derivatives 6a-g undergo alkyl mode 5-exo cyclisation to give mixtures of cis and trans N-acyl pyrrolidinones (d.e. = 54-74%). The efficiency of the process was found to be dependant upon the steric and electronic nature of the nitrogen substituent.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | SYNLETT |
| Publisher: | GEORG THIEME VERLAG |
| ISSN: | 0936-5214 |
| Date: | April 1999 |
| Number: | 4 |
| Number of Pages: | 3 |
| Page Range: | pp. 444-446 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/14587 |
Data sourced from Thomson Reuters' Web of Knowledge
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