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Ti(eta(5)-C5H5)(eta(5)-(C5H4Bu)-Bu-t)(CH2Ph)(2); a probe of the course of the petasis benzylidenation reaction
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UNSPECIFIED (1999) Ti(eta(5)-C5H5)(eta(5)-(C5H4Bu)-Bu-t)(CH2Ph)(2); a probe of the course of the petasis benzylidenation reaction. SYNLETT (1). pp. 90-92. ISSN 0936-5214
Full text not available from this repository.Abstract
The existence of the proposed benzylidene intermediate 11 in the Petasis benzylidenation procedure is supported by the isolation of cyclometallated product 8. A model is proposed which explains the empirical observation that a large acid residue and a small ester group are needed for good stereoselectivity in benzylidenation reactions.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | SYNLETT |
| Publisher: | GEORG THIEME VERLAG |
| ISSN: | 0936-5214 |
| Date: | January 1999 |
| Number: | 1 |
| Number of Pages: | 3 |
| Page Range: | pp. 90-92 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/14835 |
Data sourced from Thomson Reuters' Web of Knowledge
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