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Ti(eta(5)-C5H5)(eta(5)-(C5H4Bu)-Bu-t)(CH2Ph)(2); a probe of the course of the petasis benzylidenation reaction
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UNSPECIFIED (1999) Ti(eta(5)-C5H5)(eta(5)-(C5H4Bu)-Bu-t)(CH2Ph)(2); a probe of the course of the petasis benzylidenation reaction. SYNLETT (1). pp. 90-92. ISSN 0936-5214.
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Abstract
The existence of the proposed benzylidene intermediate 11 in the Petasis benzylidenation procedure is supported by the isolation of cyclometallated product 8. A model is proposed which explains the empirical observation that a large acid residue and a small ester group are needed for good stereoselectivity in benzylidenation reactions.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | SYNLETT | ||||
Publisher: | GEORG THIEME VERLAG | ||||
ISSN: | 0936-5214 | ||||
Official Date: | January 1999 | ||||
Dates: |
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Number: | 1 | ||||
Number of Pages: | 3 | ||||
Page Range: | pp. 90-92 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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