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Sol-gel synthesis and structure of borosilicon oxycarbide glasses

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UNSPECIFIED (1998) Sol-gel synthesis and structure of borosilicon oxycarbide glasses. JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 13 (1-3). pp. 1001-1004. ISSN 0928-0707

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Abstract

Existing sol-gel polymerization/pyrolysis routes employing two separate boron containing metal alkoxide precursors have been applied to form multi-component silicon oxycarbide glasses based on a borosilicon oxycarbide (B-Si-O-C) system. Si-29 and B-11 magic angle spinning nuclear magnetic resonance (MAS-NMR) was used to characterize the atomic structure of the gels, glasses and glass ceramics. Structural changes such as glass formation and crystal nucleation were identified by X-ray diffraction (XRD). Transmission electron microscopy (TEM) provided images of crystal nucleation and growth.

Item Type: Journal Article
Subjects: T Technology > TP Chemical technology
Journal or Publication Title: JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY
Publisher: KLUWER ACADEMIC PUBL
ISSN: 0928-0707
Date: 1998
Volume: 13
Number: 1-3
Number of Pages: 4
Page Range: pp. 1001-1004
Publication Status: Published
URI: http://wrap.warwick.ac.uk/id/eprint/14891

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