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Data for Asymmetric transfer hydrogenation of unsaturated ketones; factors influencing 1,4- vs 1,2- regio- and enantioselectivity, and alkene vs alkyne directing effects
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Hall, Thomas Howard, Adams, Hannah, Vyas, Vijyesh K., Chu, K. L. Michael and Wills, Martin (2021) Data for Asymmetric transfer hydrogenation of unsaturated ketones; factors influencing 1,4- vs 1,2- regio- and enantioselectivity, and alkene vs alkyne directing effects. [Dataset]
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Abstract
A detailed study has been completed on the asymmetric transfer hydrogenation (ATH) of a series of enones using Ru(II) catalysts. Electron-rich rings adjacent to the Cdouble bondO group reduce the level of Cdouble bondO reduction compared to Cdouble bondC. The ATH reaction can readily discriminate between double and triple bonds adjacent to ketones, reducing the double bond but leaving a triple bond intact in the major product.
Item Type: | Dataset | ||||||||||||
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Subjects: | Q Science > QD Chemistry | ||||||||||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||||||||||
Type of Data: | Experimental data | ||||||||||||
Library of Congress Subject Headings (LCSH): | Hydrogenation, Ketones -- Synthesis, Ruthenium catalysts | ||||||||||||
Publisher: | Department of Chemistry | ||||||||||||
Official Date: | 2021 | ||||||||||||
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Status: | Not Peer Reviewed | ||||||||||||
Publication Status: | Published | ||||||||||||
Access rights to Published version: | Open Access (Creative Commons) | ||||||||||||
Copyright Holders: | University of Warwick | ||||||||||||
Description: | Data record is empty. |
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