UNSPECIFIED (1998) Oxidation of the Cu(100)c(2x2)-Mn surface: epitaxial manganese oxide. Surface Science, 418 (3). pp. 521-528. ISSN 0039-6028

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Abstract

Using a combination of scanning tunnelling microscopy (STM), low energy electron diffraction and X-ray photoelectron spectroscopy the oxidation of the Cu(100)c(2 x 2)-Mn surface alloy phase has been studied. A commensurate (root 5 x root 5)R27 degrees phase is formed, the periodicity and stoichiometry of which are consistent with an epitaxial manganese oxide overlayer having a structure very similar to that of bulk Mn3O4 ("hausmannite"). Possible detailed structural models for the oxide registry are discussed, especially in the light of the observed STM images. (C) 1998 Elsevier Science B.V. All rights reserved.

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry Q Science > QC Physics
Journal or Publication Title:	Surface Science
Publisher:	ELSEVIER SCIENCE BV
ISSN:	0039-6028
Date:	14 December 1998
Volume:	418
Number:	3
Number of Pages:	8
Page Range:	pp. 521-528
Publication Status:	Published
URI:	http://wrap.warwick.ac.uk/id/eprint/14972

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