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Tetrahydrofuran (thf) solvates of tin (IV) halides: Crystal structures of trans-SnX4(thf)(2) where X = Cl, Br. Molecular modelling of the cis/trans isomers of SnX4(thf)(2)
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UNSPECIFIED (1998) Tetrahydrofuran (thf) solvates of tin (IV) halides: Crystal structures of trans-SnX4(thf)(2) where X = Cl, Br. Molecular modelling of the cis/trans isomers of SnX4(thf)(2). MAIN GROUP METAL CHEMISTRY, 21 (10). pp. 583-591. ISSN 0334-7575
Full text not available from this repository.Abstract
From studies of the SnX4-thf reaction system (thf tetrahydrofuran; X = F, CI, Br, I) we have established adduct formation, SnX4(thf)(2) for X = CI (I) and Br (Il) but recovery of unchanged starting materials for X = F and I. X-ray crystallography confirms a six coordinate structure with regular octahedral metal geometry for both (I) and (II) with the two solvent (thf) molecules in a mutually trans-arrangement in each case. Modelling studies of the cis/trans-isomers of SnX4(thf)(2) where X = CI, Br and of SnCl4(H2O)(2) have been carried out and comparisons drawn with the observed structural chemistry of these systems.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | MAIN GROUP METAL CHEMISTRY |
| Publisher: | FREUND PUBLISHING HOUSE LTD |
| ISSN: | 0334-7575 |
| Date: | October 1998 |
| Volume: | 21 |
| Number: | 10 |
| Number of Pages: | 9 |
| Page Range: | pp. 583-591 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/15236 |
Data sourced from Thomson Reuters' Web of Knowledge
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