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Synthesis of homo- and block copolymer multi-armed methacrylic star polymers by triisobutylaluminium/tert-butlyllithium initiation

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UNSPECIFIED (1998) Synthesis of homo- and block copolymer multi-armed methacrylic star polymers by triisobutylaluminium/tert-butlyllithium initiation. MACROMOLECULAR SYMPOSIA, 132 . pp. 187-196. ISSN 1022-1360

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Abstract

Methacrylate star polymers were prepared using the "arm-first" strategy of star polymer formation by the addition of ethylene glycol dimethacrylate to living linear poly(methacrylate) arms synthesised by a trialkylaluminium/ alkyllithium initiating system. Control over star molar mass is discussed for poly(methyl methacrylate) armed star polymers as is the preparation of star polymers with block copolymer arms.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Journal or Publication Title: MACROMOLECULAR SYMPOSIA
Publisher: WILEY-V C H VERLAG GMBH
ISSN: 1022-1360
Date: July 1998
Volume: 132
Number of Pages: 10
Page Range: pp. 187-196
Publication Status: Published
URI: http://wrap.warwick.ac.uk/id/eprint/15237

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