* All data was initially processed via Agilent Masshunter software into CSV files and then further processed in Iolite (version3) to give average values for each ablation line. * The data has been split to align with the 3 figures in the paper. * Concentrations were determined via microwave digestion and ICP-MS analysis. * Laser fluence is displayed as a value in units J/cm2 * All values for iron or selenium are average measurements from each standard, normalised to the corresponding average sulphur value. * Within-line relative standard deviations (RSDS) were determined for each line and then average RSD reported for each standard. * For methanol addition average selenium counts were calculated for each percentage of methanol addition, whilst maintaining a constant selenium concentration.