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Identification of erbium(III) chloride solvate ErCl3(thf)(3.5): Crystal and molecular structure of the ion-pair [trans-ErCl2(thf)(5)][trans-ErCl4(thf)(2)]
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UNSPECIFIED (1998) Identification of erbium(III) chloride solvate ErCl3(thf)(3.5): Crystal and molecular structure of the ion-pair [trans-ErCl2(thf)(5)][trans-ErCl4(thf)(2)]. JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 75 (8). pp. 435-438. ISSN 0019-4522
Full text not available from this repository.Abstract
ErCl3(thf)(3.5) has been identified by an X-ray diffraction study as the ionic salt [trans-ErCl2(thf)(5)] [trans-ErCl4(thf)(2)]. The monocation features a seven-coordinate erbium atom with a trans-ErCl2 unit (Er-Cl, 2.563(2) Angstrom) surrounded by five tetrahydrofuran molecules (Er-O, in the range 2.383(8)-2.393(8) Angstrom) in a regular pentagonal bipyramidal geometry. The anion is six-coordinate with an octahedral metal geometry comprising four equatorial chlorine atoms (Er-Cl, 2.593(3) and 2.609(3) Angstrom) and two axial tetrahydrofuran molecules (Er-O, 2.313(9) Angstrom).
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | JOURNAL OF THE INDIAN CHEMICAL SOCIETY |
| Publisher: | INDIAN CHEMICAL SOC |
| ISSN: | 0019-4522 |
| Date: | August 1998 |
| Volume: | 75 |
| Number: | 8 |
| Number of Pages: | 4 |
| Page Range: | pp. 435-438 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/15436 |
Data sourced from Thomson Reuters' Web of Knowledge
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