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Evidence for actinide metal to ligand pi backbonding. Density functional investigations of the electronic structure of [{(NH2)(3)(NH3)U}(2)(mu(2)-eta(2):eta(2)-N-2)]

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UNSPECIFIED (1998) Evidence for actinide metal to ligand pi backbonding. Density functional investigations of the electronic structure of [{(NH2)(3)(NH3)U}(2)(mu(2)-eta(2):eta(2)-N-2)]. CHEMICAL COMMUNICATIONS (16). pp. 1665-1666.

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Abstract

The electronic structure of [ {(NH2)(3)(NH3)U}(2)(mu(2)-eta(2):eta(2)-N-2)], a model for the first dinitrogen compound of an actinide, is investigated computationally using quasi-relativistic nonlocal density functional theory; the only significant U-N-2-U interaction is found to be U-->N-2 pi backbonding.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Journal or Publication Title: CHEMICAL COMMUNICATIONS
Publisher: ROYAL SOC CHEMISTRY
ISSN: 1359-7345
Official Date: 21 August 1998
Dates:
DateEvent
21 August 1998UNSPECIFIED
Number: 16
Number of Pages: 2
Page Range: pp. 1665-1666
Publication Status: Published

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