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Aqueous co-ordination chemistry using electrospray mass spectrometry of anions: metal(VI)-monosaccharide complexes (M = W or Mo)
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UNSPECIFIED (1998) Aqueous co-ordination chemistry using electrospray mass spectrometry of anions: metal(VI)-monosaccharide complexes (M = W or Mo). JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS (13). pp. 2177-2183. ISSN 0300-9246
Full text not available from this repository.Abstract
Electrospray mass spectrometry has been applied for the first time to the co-ordination chemistry of aqueous anions, using as a model system the reaction of tungstate or molybdate with galactaric (mucic) acid and galacturonic acid; 1 : 1, 2: 1 and 1 :2 complexes are found, thus confirming and extending previous solution-state studies. The gas-phase ions may undergo minor dehydration, and some decarboxylation. Nevertheless, the method is shown to provide a rapid and simple means for identifying mixtures of anionic complexes in dilute aqueous solution, even when their binding constants are modest.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS |
| Publisher: | ROYAL SOC CHEMISTRY |
| ISSN: | 0300-9246 |
| Date: | 7 July 1998 |
| Number: | 13 |
| Number of Pages: | 7 |
| Page Range: | pp. 2177-2183 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/15521 |
Data sourced from Thomson Reuters' Web of Knowledge
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