Aqueous co-ordination chemistry using electrospray mass spectrometry of anions: metal(VI)-monosaccharide complexes (M = W or Mo)
UNSPECIFIED. (1998) Aqueous co-ordination chemistry using electrospray mass spectrometry of anions: metal(VI)-monosaccharide complexes (M = W or Mo). JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS (13). pp. 2177-2183. ISSN 0300-9246Full text not available from this repository.
Electrospray mass spectrometry has been applied for the first time to the co-ordination chemistry of aqueous anions, using as a model system the reaction of tungstate or molybdate with galactaric (mucic) acid and galacturonic acid; 1 : 1, 2: 1 and 1 :2 complexes are found, thus confirming and extending previous solution-state studies. The gas-phase ions may undergo minor dehydration, and some decarboxylation. Nevertheless, the method is shown to provide a rapid and simple means for identifying mixtures of anionic complexes in dilute aqueous solution, even when their binding constants are modest.
|Item Type:||Journal Article|
|Subjects:||Q Science > QD Chemistry|
|Journal or Publication Title:||JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS|
|Publisher:||ROYAL SOC CHEMISTRY|
|Date:||7 July 1998|
|Number of Pages:||7|
|Page Range:||pp. 2177-2183|
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