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Synthesis and molecular structure of the lithiated triamidoamine [Li-3{N((CH2CH2SiBuMe2)-Me-t)(3)}(THF)(n)]
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UNSPECIFIED (1998) Synthesis and molecular structure of the lithiated triamidoamine [Li-3{N((CH2CH2SiBuMe2)-Me-t)(3)}(THF)(n)]. INORGANIC CHEMISTRY, 37 (13). 3435-+. ISSN 0020-1669
Full text not available from this repository.Abstract
Addition of THF to a pentane solution of [Li-3{N((CH2CH2SiBuMe2)-Me-t)(3)}] prepared in situ from tris-(2-aminoethyl)amine (TREN) leads to the crystallization of [Li-3{N((CH2CH2SiBuMe2)-Me-t)(3)}(THF)(n)] (n = 3). The molecular structure of the compound (n = 2) reveals a dimeric structure as shown. Two triamidoamine ligands are linked via incorporation of one amido nitrogen atom each into a Li2N2 Unit. Sublimation of the above allows isolation of the base-free compound [Li-3{N((CH2CH2SiBuMe2)-Me-t)(3)}].
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | INORGANIC CHEMISTRY |
| Publisher: | AMER CHEMICAL SOC |
| ISSN: | 0020-1669 |
| Date: | 29 June 1998 |
| Volume: | 37 |
| Number: | 13 |
| Number of Pages: | 3 |
| Page Range: | 3435-+ |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/15595 |
Data sourced from Thomson Reuters' Web of Knowledge
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