alpha,omega-dicarboxyl telechelic poly(methyl methacrylate) via radical addition-fragmentation polymerization
UNSPECIFIED (1998) alpha,omega-dicarboxyl telechelic poly(methyl methacrylate) via radical addition-fragmentation polymerization. POLYMER, 39 (14). pp. 3119-3128. ISSN 0032-3861Full text not available from this repository.
Catalytic chain transfer polymerization of benzyl methacrylate leads to a mixture of poly(benzyl methacrylate) macromonomers. Benzyl methacrylate dimer macromonomer has been isolated as a pure compound and used as a radical addition fragmentation chain transfer agent. This results in poly(methyl methacrylate) with both alpha and omega terminal benzyl methacrylate units. Catalytic hydrogenation of alpha,omega-benzyl methacrylate terminal poly(methyl methacrylate) results in evolution of toluene and formation of alpha,omega-dicarboxyl functional telechelic poly(methyl methacrylate). The products have been fully characterized by matrix assisted laser desorption time-of-flight mass spectrometry in conjunction with H-1 and C-13 n.m.r. spectroscopy. (C) 1998 Elsevier Science Ltd. All rights reserved.
|Item Type:||Journal Article|
|Subjects:||Q Science > QD Chemistry|
|Journal or Publication Title:||POLYMER|
|Publisher:||ELSEVIER SCI LTD|
|Number of Pages:||10|
|Page Range:||pp. 3119-3128|
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