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Detailed GPC analysis of poly(N-isopropylacrylamide) with core cross-linked star architecture
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Monaco, Alessandra., Drain, Ben and Becer, C. Remzi (2021) Detailed GPC analysis of poly(N-isopropylacrylamide) with core cross-linked star architecture. Polymer Chemistry, 12 (36). pp. 5229-5238. doi:10.1039/d1py00966d ISSN 1759-9962.
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Official URL: https://doi.org/10.1039/d1py00966d
Abstract
Core cross-linked star shaped polymers possess unique physical properties that can be utilized as drug transporters for biomedical applications. However, detailed analysis of these polymer structures is not straightforward. Herein, we employ multi-detector gel permeation chromatography (GPC) to elucidate structural features of cross-linked stars prepared from the polymerisation of NIPAM via Cu(0)-mediated Reversible Deactivation Radical Polymerisation. Furthermore, we aim to show how varying the arm length and the core size of the star polymers can not only affect their structural properties but also their capacity to encapsulate drug-like molecules.
Item Type: | Journal Article | ||||||||
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Subjects: | Q Science > QC Physics Q Science > QD Chemistry Q Science > QH Natural history R Medicine > RS Pharmacy and materia medica |
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Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||||||
SWORD Depositor: | Library Publications Router | ||||||||
Library of Congress Subject Headings (LCSH): | Polymers, Star-branched polymers, Drug carriers (Pharmacy), Biological transport, Biomedical engineering | ||||||||
Journal or Publication Title: | Polymer Chemistry | ||||||||
Publisher: | Royal Society of Chemistry (RSC) | ||||||||
ISSN: | 1759-9962 | ||||||||
Official Date: | 28 September 2021 | ||||||||
Dates: |
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Volume: | 12 | ||||||||
Number: | 36 | ||||||||
Page Range: | pp. 5229-5238 | ||||||||
DOI: | 10.1039/d1py00966d | ||||||||
Status: | Peer Reviewed | ||||||||
Publication Status: | Published | ||||||||
Access rights to Published version: | Open Access (Creative Commons) | ||||||||
Date of first compliant deposit: | 28 October 2021 | ||||||||
Date of first compliant Open Access: | 28 October 2021 | ||||||||
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