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Copper diimine complexes: the synthesis and crystal structures of [Cu(C10H14N2)(2)(MeOH)][BF4], [Cu(C10H20N2)(2)]Br, [{(C10H14N2)CuBr(mu-OMe)}(2)(MeOH)] and [{(C10H20N2)CuBr(mu-OMe)}(2)]
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UNSPECIFIED (1998) Copper diimine complexes: the synthesis and crystal structures of [Cu(C10H14N2)(2)(MeOH)][BF4], [Cu(C10H20N2)(2)]Br, [{(C10H14N2)CuBr(mu-OMe)}(2)(MeOH)] and [{(C10H20N2)CuBr(mu-OMe)}(2)]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS (3). pp. 381-385. ISSN 0300-9246
Full text not available from this repository.Abstract
The synthesis and structural characterisation of related novel copper-(I) and -(II) diimine complexes have been described and their application as catalysts for atom transfer polymerisation is noted. The unexpected formation of a methoxy bridged copper(II) diimine complex [{(C10H14N2)CuBr(mu-OMe)}(2)(MeOH)] 3 from the reaction of a copper(I) diimine complex with phenol is described. Compounds 3 and [{(C10H20N2)CuBr(mu-OMe)}(2)] 4 appear to be examples of a rare class of alkoxy bridged Cu-II complexes, with very few similar examples being crystallographically characterised previously.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS |
| Publisher: | ROYAL SOC CHEMISTRY |
| ISSN: | 0300-9246 |
| Date: | 7 February 1998 |
| Number: | 3 |
| Number of Pages: | 5 |
| Page Range: | pp. 381-385 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/16005 |
Data sourced from Thomson Reuters' Web of Knowledge
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