Mechanistic aspects of high-energy collision-induced dissociation proximate to the charge in saturated fatty acid N-butyl esters cationized with lithium. Evidence for hydrogen radical removal
UNSPECIFIED (1997) Mechanistic aspects of high-energy collision-induced dissociation proximate to the charge in saturated fatty acid N-butyl esters cationized with lithium. Evidence for hydrogen radical removal. In: 15th Informal Meeting on Mass Spectrometry, SMOLENICE, SLOVAKIA, MAY 12-16, 1997. Published in: RAPID COMMUNICATIONS IN MASS SPECTROMETRY, 11 (16). pp. 1808-1812.Full text not available from this repository.
The high-energy collision-induced dissociation spectra of [M+Li](+) ions of n-butyl palmitate or heptadecanoate and their labelled isotopomers containing a H-2(2)-label at the C-2, C-3 and C-4 positions are reported, As is the case for positions remote from the charge, the removal of a hydrogen radical at proximate positions has been found to be an initial and decisive fragmentation reaction when [M + Li](+) ions are subjected to high-energy collision-induced dissociation, It is also demonstrated that direct C-C cleavage involving gamma bonds relative to the carbonyl bond or bonds more remote from the charge may be regarded as a secondary fragmentation route, Direct C-C cleavage of the beta bond should, however, be considered as a reaction competitive with C-H cleavage in the formation of the corresponding distonic ions. (C) 1997 John Wiley & Sons, Ltd.
|Item Type:||Conference Item (UNSPECIFIED)|
|Subjects:||Q Science > QD Chemistry
Q Science > QC Physics
|Journal or Publication Title:||RAPID COMMUNICATIONS IN MASS SPECTROMETRY|
|Publisher:||JOHN WILEY & SONS LTD|
|Number of Pages:||5|
|Page Range:||pp. 1808-1812|
|Title of Event:||15th Informal Meeting on Mass Spectrometry|
|Location of Event:||SMOLENICE, SLOVAKIA|
|Date(s) of Event:||MAY 12-16, 1997|
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