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A cis-octahedral dichloro complex of Fe-III with a tetradentate dipyridyl-diamino ligand

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UNSPECIFIED (1997) A cis-octahedral dichloro complex of Fe-III with a tetradentate dipyridyl-diamino ligand. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 53 (Part 10). pp. 1385-1387. ISSN 0108-2701

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Abstract

In [N,N'-bis(2-pyridylmethyl)-1, 3-propanediamine-N,N',N '',N''']dichloroiron(III) perchlorate, [FeCl2(C15H20N4)]ClO4, the linear tetradentate Ligand adopts the cis-beta configuration which provides a favourable geometry for the six-membered chelate ring. The Fe-N distances show lengthening from the trans influence of the chloride ligands, with Fe-N-py values of 2.152 (3) and 2.179 (3) Angstrom, and Fe-N-amine distances of 2.141 (4) and 2.178 (4) Angstrom.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Journal or Publication Title: ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
Publisher: MUNKSGAARD INT PUBL LTD
ISSN: 0108-2701
Date: 15 October 1997
Volume: 53
Number: Part 10
Number of Pages: 3
Page Range: pp. 1385-1387
Publication Status: Published
URI: http://wrap.warwick.ac.uk/id/eprint/16303

Data sourced from Thomson Reuters' Web of Knowledge

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