Häkkinen, Satu, Dyer, Billy, Kerr, Andrew and Perrier, Sébastien (2022) Putting the RAFT in GRAFT : intermolecular graft exchange between bottlebrush polymers using reversible addition–fragmentation chain transfer. Polymer Chemistry, 13 (4). pp. 479-484. doi:10.1039/d1py01510a ISSN 1759-9954.

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Abstract

A versatile synthetic methodology is presented for the preparation of graft copolymers with mixed graft distributions using reversible addition–fragmentation chain transfer (RAFT). The approach harnesses the ability of Z group-tethered grafts to fragment off the backbone to facilitate intermolecular graft exchange reactions between distinct starting materials.

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science, Engineering and Medicine > Science > Chemistry Faculty of Science, Engineering and Medicine > Medicine > Warwick Medical School
Library of Congress Subject Headings (LCSH):	Graft copolymers, Polymerization, Copolymers -- Synthesis, Addition polymerization, Fragmentation reactions
Journal or Publication Title:	Polymer Chemistry
Publisher:	Royal Society of Chemistry
ISSN:	1759-9954
Official Date:	28 January 2022
Dates:	Date Event 28 January 2022 Published 20 December 2021 Available 17 December 2021 Accepted
Volume:	13
Number:	4
Page Range:	pp. 479-484
DOI:	10.1039/d1py01510a
Status:	Peer Reviewed
Publication Status:	Published
Access rights to Published version:	Open Access (Creative Commons)
Date of first compliant deposit:	16 March 2022
Date of first compliant Open Access:	24 March 2022
RIOXX Funder/Project Grant:	Project/Grant ID RIOXX Funder Name Funder ID Scholarship Lubrizol http://dx.doi.org/10.13039/100007036

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