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Unusual features in the triplet state EPR spectrum of 3,5-dichloro-4-aminophenyl cation
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UNSPECIFIED (1997) Unusual features in the triplet state EPR spectrum of 3,5-dichloro-4-aminophenyl cation. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 108 (2-3). pp. 149-153. ISSN 1010-6030
Full text not available from this repository.Abstract
The tripler ground state of the 3,5-dichloro-aminophenyl cation (Ar-3(+)), generated by photolysis at 77 K of the parent arenediazonium salt, exhibits the strongest dipolar interaction in its EPR spectrum (D > 0.3 cm(-1)) found so far for any known aryl cation. It also shows high-energy site splitting, as detected by EPR for several other cations, producing two distinct forms (type A with D = 0.3066 cm(-1) and type B with D = 0.3410 cm(-1)). Ar-3(+) and certain other aryl cations also show electronic absorption spectra composed of two or three distinct bands. (C) 1997 Elsevier Science S.A.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY |
| Publisher: | ELSEVIER SCIENCE SA LAUSANNE |
| ISSN: | 1010-6030 |
| Date: | 15 August 1997 |
| Volume: | 108 |
| Number: | 2-3 |
| Number of Pages: | 5 |
| Page Range: | pp. 149-153 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/16398 |
Data sourced from Thomson Reuters' Web of Knowledge
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