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The role of structural transformations in magnetic behaviour of fluorosilicates of 3d transition metals

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UNSPECIFIED (1997) The role of structural transformations in magnetic behaviour of fluorosilicates of 3d transition metals. JOURNAL OF PHYSICS-CONDENSED MATTER, 9 (34). pp. 7161-7171. ISSN 0953-8984

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Abstract

The stability of the structural phases in the fluorosilicate hexahydrates of some 3d transition metals MSiF6.6H(2)O where M = Mn, Fe, Co and Ni is studied in a wide range of temperatures and pressures. The results are generalized in the form of a P-T phase diagram of crystal states. The triple points, new high-pressure phases and wide ranges of metastable states between them have been discovered. The correspondence between structural and magnetic P-T phase diagrams of the series is established.

Item Type: Journal Article
Subjects: Q Science > QC Physics
Journal or Publication Title: JOURNAL OF PHYSICS-CONDENSED MATTER
Publisher: IOP PUBLISHING LTD
ISSN: 0953-8984
Date: 25 August 1997
Volume: 9
Number: 34
Number of Pages: 11
Page Range: pp. 7161-7171
Publication Status: Published
URI: http://wrap.warwick.ac.uk/id/eprint/16442

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