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Interactions of Pb and Te atoms with graphene

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Gong, Chuncheng, Robertson, Alex W., He, Kuang, Ford, Camden, Watt, Andrew A. R. and Warner, Jamie H. (2014) Interactions of Pb and Te atoms with graphene. Dalton Transactions, 43 (20). pp. 7442-7448. doi:10.1039/c4dt00143e ISSN 1477-9226.

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Official URL: http://dx.doi.org/10.1039/c4dt00143e

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Abstract

PbTe nanocrystals were deposited onto the surface of graphene and used as a reservoir of Pb and Te atoms. Electron beam irradiation at 80 kV caused Pb and Te atoms to mobilize and disperse across the surface of graphene. We studied the dynamics of these atoms in real time using aberration-corrected transmission electron microscopy. The Pb and Te atoms were found to attach to the surface layer of amorphous carbon that resides upon the graphene, as well as its edge. Pb and Te atoms were not found residing on pristine graphene, but were found to bond to the free edge states along graphene hole edges. Small PbTe nanoclusters tended to only form on the surface of the amorphous carbon regions and not on pristine graphene.

Item Type: Journal Article
Divisions: Faculty of Science, Engineering and Medicine > Science > Physics
Journal or Publication Title: Dalton Transactions
Publisher: Royal Society of Chemistry
ISSN: 1477-9226
Official Date: 28 May 2014
Dates:
DateEvent
28 May 2014Published
20 February 2014Available
10 February 2014Accepted
15 January 2014Submitted
Volume: 43
Number: 20
Page Range: pp. 7442-7448
DOI: 10.1039/c4dt00143e
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Open Access (Creative Commons)
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