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A perspective on femtosecond pump–probe spectroscopy in the development of future sunscreens
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Whittock, Abigail L., Abiola, Temitope T. and Stavros, Vasilios G. (2022) A perspective on femtosecond pump–probe spectroscopy in the development of future sunscreens. The Journal of Physical Chemistry A, 126 (15). pp. 2299-2308. doi:10.1021/acs.jpca.2c01000 ISSN 1089-5639.
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WRAP-perspective-femtosecond-pump–probe-spectroscopy-development-future-sunscreens-Stavros-2022.pdf - Published Version - Requires a PDF viewer. Available under License Creative Commons Attribution 4.0. Download (3825Kb) | Preview |
Official URL: https://doi.org/10.1021/acs.jpca.2c01000
Abstract
Given the negative impacts of overexposure to ultraviolet radiation (UVR) on humans, sunscreens have become a widely used product. Certain ingredients within sunscreens are responsible for photoprotection and these are known, collectively herein, as ultraviolet (UV) filters. Generally speaking, organic UV filters work by absorbing the potentially harmful UVR and dissipating this energy as harmless heat. This process happens on picosecond time scales and so femtosecond pump–probe spectroscopy (FPPS) is an ideal technique for tracking this energy conversion in real time. Coupling FPPS with complementary techniques, including steady-state spectroscopy and computational methods, can provide a detailed mechanistic picture of how UV filters provide photoprotection. As such, FPPS is crucial in aiding the future design of UV filters. This Perspective sheds light on the advancements made over the past two years on both approved and nature-inspired UV filters. Moreover, we suggest where FPPS can be further utilized within sunscreen applications for future considerations.
| Item Type: | Journal Article | |||||||||||||||
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| Subjects: | Q Science > QC Physics R Medicine > RS Pharmacy and materia medica |
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| Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | |||||||||||||||
| SWORD Depositor: | Library Publications Router | |||||||||||||||
| Library of Congress Subject Headings (LCSH): | Spectrum analysis, Femtosecond lasers, Ultraviolet radiation -- Physiological effect, Sunscreens (Cosmetics) | |||||||||||||||
| Journal or Publication Title: | The Journal of Physical Chemistry A | |||||||||||||||
| Publisher: | American Chemical Society | |||||||||||||||
| ISSN: | 1089-5639 | |||||||||||||||
| Official Date: | 21 April 2022 | |||||||||||||||
| Dates: |
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| Volume: | 126 | |||||||||||||||
| Number: | 15 | |||||||||||||||
| Page Range: | pp. 2299-2308 | |||||||||||||||
| DOI: | 10.1021/acs.jpca.2c01000 | |||||||||||||||
| Status: | Peer Reviewed | |||||||||||||||
| Publication Status: | Published | |||||||||||||||
| Access rights to Published version: | Open Access (Creative Commons) | |||||||||||||||
| Date of first compliant deposit: | 25 April 2022 | |||||||||||||||
| Date of first compliant Open Access: | 26 April 2022 | |||||||||||||||
| RIOXX Funder/Project Grant: |
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