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Luminescence, spectroscopy, lifetimes and quenching mechanisms of excited states of uranyl and other actinide ions

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UNSPECIFIED (1997) Luminescence, spectroscopy, lifetimes and quenching mechanisms of excited states of uranyl and other actinide ions. [Journal Item]

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Abstract

A survey is made of the kinetics of luminescence decay and of quenching of the excited uranyl ion [UO22+]*. Attention is concentrated on post-1975 literature. The spectroscopy and electronic character of the excited state are explored as well as its modes of spontaneous decay in fluids, glasses, microheterogeneous media and crystalline solids. Its quenching, both physical and chemical, is examined from mechanistic viewpoints, encompassing electron-, energy-and hydrogen-atom transfer. Shorter coverage is made of the photochemistry of uranyl ion and of the application of its luminescence in analytical chemistry.

Item Type: Journal Item
Subjects: Q Science > QD Chemistry
Journal or Publication Title: PROGRESS IN REACTION KINETICS
Publisher: SCIENCE & TECHNOLOGY LETTERS
ISSN: 0079-6743
Date: 1997
Volume: 22
Number: 2
Number of Pages: 53
Page Range: pp. 87-139
Publication Status: Published
URI: http://wrap.warwick.ac.uk/id/eprint/16492

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