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Geometrical isomers of ScCl3(THF)(x)(H2O)(3-x): isolation and crystal structure of the compound where x=2
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UNSPECIFIED (1997) Geometrical isomers of ScCl3(THF)(x)(H2O)(3-x): isolation and crystal structure of the compound where x=2. POLYHEDRON, 16 (20). pp. 3485-3487. ISSN 0277-5387
Full text not available from this repository.Abstract
Controlled hydrolysis of ScCl3(THF)(3) results in the replacement of one tetrahydrofuran molecule to provide colourless crystals of ScCl3(THF)(2)(H2O). An X-ray structure determination of this 'mixed' solvate shows discrete six co-ordinate scandium atoms bonded to three chlorine atoms and three O-donor solvent molecules in a mer-octahedral arrangement. Sc-Cl2.399(3), 2.477(3), 2.478(3) Angstrom, Sc-O(H2O) 2.197(3) Angstrom and Sc-O(THF) 2.170(4), 2.172(4) Angstrom. (C) 1997 Elsevier Science Ltd.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | POLYHEDRON |
| Publisher: | PERGAMON-ELSEVIER SCIENCE LTD |
| ISSN: | 0277-5387 |
| Date: | 1997 |
| Volume: | 16 |
| Number: | 20 |
| Number of Pages: | 3 |
| Page Range: | pp. 3485-3487 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/16493 |
Data sourced from Thomson Reuters' Web of Knowledge
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